D'you think Mas has gone? It's mid-week, and there's been no sign of the homoeopaths during office hours (I'd guess they're posting from "work" computers, whatever that means).
I thought I'd have a quick trawl through the thread and see what they were really on about. Syed was pretty straightforward in a way, he says he can show that a homoeopathic remedy has an effect, either on a healthy person (to make them ill) or a sick person (to make them better). No response to suggested protocol for proving this beyond the influence of subjectivity.
Mas seems to have stuck on two basic points which are difficult to relate to each other - essentially his statements seem to refer either to the assertion that chemical reactions take place during dilution and succussion and so the number of molecules present at each dilution step will not be according to the simple calculation, or to the implication (not apparently asserted directly) that a significantly non-representative portion of the molecules in the solution may be aspirated when the subsequent dilution is being prepared.
So I thought I'd try to address them again, in the (pretty vain) hope that he'll pick up on them if he comes back.
To take the first point, here is one of his statements relating to that assertion.
I said earlier that due to chemical break down and building up of new molecules, avogadro's law cannot be applied in the same manner as it was stated by your friends. Simple is that, for each dilution, 2, 3, or 30 the chemical change has been occured, hence for each chemical build up and breakdown you have to take one mole again.
I wonder if this is down to a simple misunderstanding?
We've all acknowledged several times that when a salt dissociates in solution, the total number of moles (of everything together) increases. For example, sticking to the great hepatitis cure, Na<SUB>2</SUB>SO<SUB>4</SUB>, this salt contains three ions. So, if you start with a mole of sodium sulphate salt, and dissolve it, you do end up with two moles of sodium ions and one mole of sulphate ions.
Is it possible that Mas's extensive studies of chemistry have simply got as far as this elementary fact, and he has seized on it as "proof" that moles multiply as substances are diluted? Without actually understanding anything further?
It is of course perfectly obvious to anyone who got anywhere near O grade chemistry that such an assumption is nonsense. The dissolution which multiplies the number of moles present by three occurs once only, and after that the number remains constant. The number of
atoms of the original substance is
always constant, no matter how they are arranged in macromolecules or small molecules, salts or ions. Without new atoms essential for the remedy constituents (sodium and sulphur in this case) being introduced to the process, no further sodium sulphate can ever be produced, even if it were possible to rob some of the water molecules of their oxygen.
He speaks airly of "each chemical build up and breakdown" without seeming to realise that nothing can "build up" out of nothing, so no further molecules or ions of the actual remedy substance can ever be produced. If the remedy substance contains elements other than hydrogen, oxygen and carbon (those which are added in the solvent, assuming that's a water/alcohol mixture), then the building blocks to form more of the substance simply do not exist.
Regarding "breakdown", once the ions have dissociated, they cannot break down further. Again, homoeopathy does not split the atom (or so far as we know Mas is not claiming this), therefore if he started with two moles of sodium (albeit derived from one mole of sodium sulphate), two moles of sodium is all he will ever have.
Even Kumar seemed to catch on at one point. If it is asserted that significant chemical reactions are taking place between solvent and solute, it is essential to show the exact reaction(s) in detail for each different solute you're talking about. As we know, for many of the materials homoeopathy uses, no such reaction occurs. Geni mentioned the most obvious, helium. Unfortunately, though, I don't expect Mas ever to address these points, he'll simply continue to ribbit on about unspecified "chemical changes" without explaining himself.
And then he'll move to his other (and apparently unrelated) point, evenness of distribution in solution. Here is his statement about that.
When a single drop from 1st potency (which was prepared according to the ratio 1/99) was taken into 2nd bottle, can you confirm that the exact ratio of "starting material" was been transfered?
Remember, 1st potency was prepared with the ratio 1/99 i.e one drop of starting material was taken and 99 drops of fresh pure solvent (alcohol) was added and then it was jerked 10 times. The lonly drops was got mixed and now you have to take one drop from the previous potency as "new starting material".
Can you confirm that this new drop which was taken as new starting material contain 1/99 ratio of probablity?
Remember, according to probality law, it is quite possible that the 2nd starting material drop may not contain any molecule of 1st starting material (because that drop was picked up blindly from the bottle) and it may or may not contain 50% of the 1st starting material or may contain 99% of the starting material.
Now, just as an aside, I noticed a striking resemblance between this and an
earlier post from Steenkh:
Maybe, during the potentization process, the active ingredient molecule starts feeling very lonely, and when the 10th part is taken out in order to perform the next dilution, the molecule decides to become more potent and rushes to the pipette in order not to be chucked out with the 9/10 of the solution?
No, surely it would be quite unworthy to suspect that Mas actually dreamed up this entire load of nonsense after reading Steenkh's tongue-in-cheek comment. Surely not?
Now, remember that Mas is claiming to relate all this to probability theory. In a part of his writing from another source quoted by Geni he seemed to have a degree of understanding of probability. However, the way he expressed this query allowed no room for the application of it.
When a single drop from 1st potency (which was prepared according to the ratio 1/99) was taken into 2nd bottle, can you confirm that the exact ratio of "starting material" was been transfered?
(My italics.) Well, if we were able to count molecules, theoretically, no. However, that's not the same as agreeing that there is any realistic probability that we might get either no molecules or all the molecules in the relevant drop.
Badly Shaved Monkey covered this, but I'll recap.
Supposing you have a mole of remedy particles in your first-stage preparation. That is 602,214,199,000,000,000,000,000,000 particles (molecules, ions, whatever form it is in, in this particular solvent). Well, you can see even now from the string of zeros at the end that this is an approximation. There are nine significant figures, so it's a pretty damn good approximation, but the last 18 orders of magnitude are space-fillers.
So, you take 1% of this. To be exact, this would mean (as far as the accuracy of the available figures goes) 6,022,141,990,000,000,000,000,000 molecules. Dr. Mas asks us whether we can guarantee
exactly that number of molecules. We agree, no. But Mas is trying for the false dilemma here.
He seems to think that if he can get us to agree that it probably won't be
exactly 6,022,141,990,000,000,000,000,000 molecules, then it's just as likely to be all 602,214,199,000,000,000,000,000,000, or none!
No, Mas. We point out that the probability theory you yourself invoke dictates that the further from the 6,022,141,990,000,000,000,000,000 figure you go, the
less likely it is that this will be the number of molecules transferred.
I myself have done experiments to check pipetting accuracy. It's simple. You just pipette out your aliquot, then measure what is in it to see if it's close enough to what it should be. I did it with radioactive isotopes, so that all I had to do was measure the radiation to see whether I had what I was supposed to have. I can tell you that a good, careful bench-worker should be able to achieve less than 2% variation in pipetting precision, and that even a slap-dash worker will manage 5% variation.
So, if we assume that the 6,022,141,990,000,000,000,000,000 is absolute, rather than a nine-significant-figure approximation, a careful worker could guarantee to get between 6,142,584,829,800,000,000,000,000 and 5,901,699,150,200,000,000,000,000 molecules, while a slap-dash operator would still manage between 6,323,249,089,500,000,000,000,000 molecules and 5,721,034,890,500,000,000,000,000 molecules.
Therefore, I would assert that yes, if you take 1% of a mole of molecules, you will definitely have somewhere between 6,323,249,089,500,000,000,000,000 molecules and 5,721,034,890,500,000,000,000,000 molecules at an outside estimation.
Mas, even if you assume that
every time you do this, you are going to get the higher of these numbers (which is itself highly improbable, just as getting heads 30 times in a row if you toss a coin is highly improbable), you still run out of molecules round about where we said you did, about the 12C region. Playing around the edges of the caculation like this can't alter that point by more than a couple of dilution steps, at the very outside chance.
Aha, I hear you say, but you are assuming that mixing of the solution is complete and uniform. Indeed I am. You mentioned ten "jerks" as the mixing process. Well, that's as may be, I've seen film of homoeopathic remedies being prepared where they used a vortex mixer at each stage, and that's guaranteed to give complete mixing of a solution. Never mind, stick with your "ten taps".
Ten (brisk) taps is easily sufficient to ensure even mixing of any true solution. I can prove this by experiment if required. So for soluble remedies, end of argument.
Suspensions are slightly different, in that they will settle out under the influence of gravity. Yes, some homoeopathic remedies are prepared as suspensions, when the starting material is insoluble. If you were very careful to keep the container upright, and not to tap too hard, and/or then left the container for some time in the upright position, yes, under these special conditions you could get a long way from the figures above.
I know a lot about this, because it's similar to preparing blood samples for blood cell counting. Blood cells are in suspension, and tend to settle if left standing. All one does, however, is invert the container up and back about six times, before
immediately pipetting out the aliquot. You can get machines that do this for you. YOU WOULD ACTUALLY HAVE TO TRY QUITE HARD TO SCREW THIS UP.
So, do we know for a fact that when preparing remedies from suspensions, homoeopaths deliberately leave the container to stand for several minutes before pipetting out the aliquot? And then, rather than take material from the top of the container (the easy, obvious move), they deliberately delve down into the bottom of the container with the point of the pipette?
Now, how come that isn't ever made clear on homoeopathic web sites which boast about how carefully remedies are prepared?
So, no way at all a 30C potency of a soluble remedy can possibly have any molecules left in it, even if the operator is really remarkably cack-handed. We might concede some presence of insoluble remedies in suspension, however, only if it can be shown that the protocol for preparation is deliberately designed to give an unrepresentatively high pick-up of particles at each stage. And in fact all the evidence we have from other homoeopaths suggests the contrary, that pains are taken to ensure as even mixing as possible.
To suggest that anything else is theoretically possible, is pretty much like suggesting it's possible that a brick might fall upward because of the random Brownian motion of the air particles all hitting it in the right orientation at the same time. Would you leave your foot under a brick on this probability?
And even once one has disposed of all that silliness, it's still necessary to point out that Mas didn't just suggest it might be that the 1% drop contained 50% or 99% of the molecules (and the brick might hover in mid-air....), he also conceded that
it is quite possible that the 2nd starting material drop may not contain any molecule of 1st starting material
So, is he ever going to explain to us how come, even by his own crazy interpretation of the situation, he can assure us that this never happens at any time during any stage of the preparation of any homoeopathic remedy, anywhere in the world?
Now, Dr. Mas, did you understand all that? If not, is there anything you would like to have explained more clearly? If you did understand it, would you care to come back on any points in relation to your own theories?
Even if all this is a bit much for you, could you at least answer these two very simple questions?
- Do you maintain that every bottle of every potency has some remedy substance in it? If not, are the ones without any molecules inactive, and what are my chances of buying an "active" bottle in my local shop?
- if your remedy contains an atom of sulphur, and there is no sulphur in the solvent you are using to make the dilutions (and we recall how insistent several homoeopaths have been about the purity of the materials used), how can you obtain any more of the remedy substance as you make further dilutions?[/list=1]I hope to hear from you very soon.
Rolfe.