A temperature of infinity, minus infinity and zero all seem to be states of infinite entropy; The same thing. This looks suspiciously like it could benefit from the no/ni null vectors
from Conformal Geometric Algebra. This might lead to a more elegant formulation of the same theory. But I'm not sure, which is why I asked. Maybe if I continue with this idea it
will turn out to be nonsensical; Maybe I stumble upon something else that is interesting. Who knows? At least, it will increase my understanding of the subjects. That purpose
is good enough for me.
Absolute zero temperature is not a state of infinite entropy because it is by definition a state of zero absolute entropy. Absolute zero temperature was actually defined as the temperature at which the unique entropy of a system reaches zero.
https://en.wikipedia.org/wiki/Second_law_of_thermodynamics
‘With this we can only obtain the difference of entropy by integrating the above formula. To obtain the absolute value, we need the Third Law of Thermodynamics, which states that S=0 at absolute zero for perfect crystals.’
So until the third law of thermodynamics was introduced, there really was a paradox in thermodynamics! The value of entropy, and therefore temperature, of a material in any container increased with the volume of the container. Therefore, there is no state of thermal equilibrium! One could induce heat flow by joining boxes with different volume!
The real paradox came about because the laws of thermodynamics 0, 1 and 2 do not provide any unique value of entropy. The laws of classical mechanics and classical electrodynamics GUARANTEE that the value of entropy. Yes, Bolzmann showed how to calculate the entropy of a closed container of gas. However, one can change the entropy merely by joining join two identical containers of material together. This is illustrated by Gibbs paradox.
https://en.wikipedia.org/wiki/Gibbs_paradox
Gibbs himself considered the following problem that arises if the ideal gas entropy is not extensive.[1] Two identical containers of an ideal gas sit side-by-side. There is a certain amount of entropy S associated with each container of gas, and this depends on the volume of each container. Now a door in the container walls is opened to allow the gas particles to mix between the containers. No macroscopic changes occur, as the system is in equilibrium. The entropy of the gas in the two-container system can be easily calculated, but if the equation is not extensive, the entropy would not be 2S. In fact, the non-extensive entropy quantity defined and studied by Gibbs would predict additional entropy. Closing the door then reduces the entropy again to 2S, in supposed violation of the Second Law of Thermodynamics.
…
The paradox is averted by concluding the indistinguishability (at least effective indistinguishability) of the particles in the volume. This results in the extensive Sackur–Tetrode equation for entropy, as derived next.’
The third law of thermodynamics was introduced to eliminate the paradox in thermodynamics. Unfortunately, the third law of thermodynamics is inconsistent with classical mechanics and classical thermodynamics because every classical particle is distinguishable.
https://en.wikipedia.org/wiki/Third_law_of_thermodynamics
‘The third law of thermodynamics is sometimes stated as follows, regarding the properties of systems in equilibrium at absolute zero temperature:
The entropy of a perfect crystal at absolute zero is exactly equal to zero.
At absolute zero (zero kelvin), the system must be in a state with the minimum possible energy, and the above statement of the third law holds true provided that the perfect crystal has only one minimum energy state. Entropy is related to the number of accessible microstates, and for a system consisting of many particles, quantum mechanics indicates that there is only one unique state (called the ground state) with minimum energy.[1] If the system does not have a well-defined order (if its order is glassy, for example), then in practice there will remain some finite entropy as the system is brought to very low temperatures as the system becomes locked into a configuration with non-minimal energy. The constant value is called the residual entropy of the system.[2]’
This was a real paradox, not some half-baked intuition.There is no lowest temperature thermal equilibrium in classical mechanics because there is no ground state.
Quantum mechanics resolved this paradox because it showed that there could be a true ground state. Point particles are actually indistinguishable.
https://en.wikipedia.org/wiki/Identical_particles
‘Identical particles, also called indistinguishable or indiscernible particles, are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to elementary particles such as electrons, composite subatomic particles such as atomic nuclei, as well as atoms and molecules. Quasiparticles also behave in this way. Although all known indistinguishable particles are "tiny", there is no exhaustive list of all possible sorts of particles nor a clear-cut limit of applicability; see particle statistics #Quantum statistics for detailed explication.’
Negative entropy is also not infinite entropy. A negative real number is not infinite. The are posters who are talking about ‘infinity’ are referring to some odd calculations using the mathematical theory of limits. An operationally equivalent way to say this is that they are using the concept of hyper real numbers.
I know ‘hyper reals’ are a bit fancier than limits, but hyper real has at one advantage. The English language treats infinity as a number, not as an operation. So it sounds a little better to talk about a temperature ‘passing through infinity’ then ‘starting a new sequence of temperatures’.
However, this may be just a matter of semantics. The physical ‘paradox’ that I find interesting is Gibbs paradox. I don’t think scientists have solved that 'inconsistently completely. I suspect that some of the paradoxes in quantum mechanics feed into the Gibbs paradox.
What do you think about Gibbs paradox as it relates to quantum mechanics? Is the Gibbs paradox still a real paradox?
