Again, does anyone know if the "proof of principle" experiments have been done, specifically at the concentrations we are talking about?
There are highschool-level experiments out there that are designed to test this. They are aimed at teaching highschool students about the effects of CO2 on global warming precisely how I've described, but they use far higher concentrations of CO2 than exist (or will ever exist) in the atmosphere.
We are talking about nearly negligible levels of change year-to-year in overall concentration of CO2, and I'd like to see if such experiments have been done at the concentrations described. I think an adequate climatologic model can be conducted in the laboratory that would prove the principle of CO2 heat re-radiation and it's actual effect on the surrounding "atmosphere" within the contained, controlled setting.
To me, this seems paramount. Right now all we have is observation and correlation, with subsequent forecasting based on the belief that those observations and correlations are causative. I'm just asking if there has ever been a proof of concept study done.
It also seems to me that we should be able to pretty accurately predict, from the actual known physical properties of CO2 ability to absorb photon energy, reach a higher energy state, then re-radiate that energy at infrared wavelengths as it returns to the ground state, what the magnitude of effect would be on an individual molecular basis. This could then be further extrapolated based on amount of energy put into the system times the total number of molecules exactly how much energy would be directly re-radiated, in the form of heat, from a group of CO2 molecules. This prediction could then be tested in the laboratory as I've described above.
This seems rather simple to me. All it requires is doing some calculations, based on the number of photon strikes a CO2 molecule would encounter during different days with different amounts and periods of sunlight. These experiments and calculations may have been done. Someone here (there are a lot of very intelligent and well-informed people participating on this forum) may know where they are or if they exist. I'm hoping that someone will share this info, if it exists. The current literature, and it's a lot, never seems to describe this in a physical chemistry sense. If it is out there, I'd just like to read it.
Thanks!
-Dr. Imago