Lemon does not help food move through the GI tract. Lemon is not an antacid (quite the opposite). Lemon does not help bicarbonate work. Everyone should drink water, lemonized or not. It's the water that does the work, not the lemon. Lemon does not cleanse the liver, increase expectoration or thin mucus. Dr. Dean is a quack. If you don't believe so, cite her peer-reviewed papers behind the claims you have posted.
KS, everything is a chemical, not just stuff made in labs, plants and factories. Natural stuff is full of natural chemicals. Presence or absence of synthetic chemicals does not necessarily affect the nutritive value of a food. For example, addition of synthetic ascorbic acid to apple slices does not render them dangerous. In contrast, the presence of too much natural aflatoxin in peanuts will do you lots of harm.
Don't fall for the popular but wrong platitudes that nature won't hurt you. Most of the deadliest substances known ot us are natural and most of these are complex enough that they can't be synthesized.
We are intelligent, analytical people. We know that molecules have no way to tell whether they're synthetic or natural so that's what draws skepticism to your statements. We also value statements and posits that are backed up by data, not whimsy. We would no sooner accept just-so statements that people like Dr. Dean make than we would believe Uri Geller is psychic. All statements must be backed up.
Believing woo does make you less of a skeptic than not believing woo. The "natural is better than synthetic" woo has been around for quite a while and there are very few authoritative sources speaking against it so this is really a pablum woo. There is no evidence for it.
However, as far as woo is concerned, this type of woo won't do you any harm as long as you don't believe it's claims that certain intake can cure diseases. If you want to spend the extra cash on food grown in certain ways, that's your choice. All that does is cost you a few more dollars every week. However, don't believe people who tell you that a certain type of calcium will cure cancer or that lemon will detoxify a specific chemical out of bone, fat or liver. Go see a doctor, and not a naturopathic one.