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Hmm.

Roy presents no direct evidence for the existence of water polymers, but merely inference, supposition - and a citation of the work of Martin Chaplin.

Chaplin presents no direct evidence for the existence of water polymers, but merely inference, supposition - and a citation of single
paper by Muller, Bogge and Diemann in Inorganic Chemistry Communications, volume 6, number 1, January 2003.

Okay, now we're getting somewhere! Abstract:
A (H2O)100 nanodrop of water was found in the cavity of a spherical polyoxomolybdate cluster of the type {(Mo)Mo5}12(spacer)30 and structurally characterised. The molecules within the water cluster are arranged in three concentric shells with radii of 3.84–4.04, 6.51–6.83 and 7.56–7.88 Å spanned by 20, 20, and 60 molecules, respectively. The first shell dodecahedron is formed exclusively by 20 hydrogen bonds (O
22ef.gif
O=2.77–2.92 Å) in the centre and 12 (H2O)5 pentagons (O
22ef.gif
O=2.66–2.81 Å) formed by hydrogen bonds at the periphery, i.e., the third shell. Each of the H2O molecules of the second (dodecahedral) shell connects the molecules from three different pentagons of the third shell with one molecule of the central dodecahedron.
Some significant points here: They are not talking about water polymers, but of supramolecular H2O assemblies (their own term). They are not talking about free liquid water, but of the effects of nano-scale encapsulation.

Unfortunately, only the abstract is available online unless someone is at a university with a subscription to the journal or wants to pop $30 for a pdf.

Here's another link to that research, with some additional details. Again, no polymers, and nano-scale confinement.

Looks like Chaplin and Roy have taken a very specific observation and runnnnnnnnnnnn with it.

(Interestingly, Muller has co-authored several papers with a Dr. Soumyajit Roy - wonder if that's a relation. Probably not, it's a common enough Indian surname. I just blinked when I saw the name popping up in the citations.)
 
Personalized Results 1 - 10 of about 171,000,000 for structure water. (0.17 seconds)

Personalized Results 1 - 10 of about 24,000,000 for structure liquid water. (0.22 seconds)

In a hurry to dispute every sentence, too many mistakes are being made. Watch it out.

Murthy
Try again. Learn how to use Google first.

"structure of water"
"structure of liquid water"

It's a minor point, but he does bring it up again later in the article, so it's worth noting that it's off by two orders of magnitude.
 
Personalized Results 1 - 10 of about 171,000,000 for structure water. (0.17 seconds)

Personalized Results 1 - 10 of about 24,000,000 for structure liquid water. (0.22 seconds)

In a hurry to dispute every sentence, too many mistakes are being made. Watch it out.

Murthy
Quote marks ("") matter in a database search. Slow down in your hurry to dispute every sentence, you might make fewer mistakes.
 
I am not accusing Roy of cheating.
Neither am I, I must add. But he's looking at some very subtle anomalies, and producing a great deal of speculation. To join those dots together requires very careful testing and verification, and there isn't any.
 
The "493546" Ethanol is potable, anhydrous ethanol. It is not as clean as the spectroscopic grade. No matter, neither corresponds to the spectrum of pure ethanol shown on p. 28 of the lecture you are promoting. Most particularly, and this is very important (so- pay attention), the slide on p. 28 shows an absorption max. at 325 nm which does not belong to pure ethanol.

The "nux vomica" spectra could simply be potable alcohol. There are many possible explanations for the slight differences among them. PixyMisa is correct- stringent controls are required before one can claim the "differences" are real.

I am not accusing Roy of cheating. I am questioning his competence in this matter.

Nux.vomica dilutions are not made with spectroscopic grade ethanol. When you want to compare a commercially available 6c potency of nux.v, with plain ethanol, you have to use the same type of ethanol which was used for its preperation. Simple basics.

Murthy
 
Muller's work on polyoxomolybdates is interesting. I hadn't run across those before. So some good has come out of this thread. :)
 
Quote marks ("") matter in a database search. Slow down in your hurry to dispute every sentence, you might make fewer mistakes.

Did Dr.Roy say that he used quote marks? When the results you are getting are different from what he quoted, why didn't you pause and think about what could have made a difference? Heavens are not going to fall, wheher it is 8 million hits or 17 million hits.

Instead of trying to dispute every sentence, concentrate on the main issues.

Murthy
 
Nux.vomica dilutions are not made with spectroscopic grade ethanol.
Do you know what a Straw Man is? I did not say Nv solutions are made with spec grade ethanol. Your statement is meaningless.
When you want to compare a commercially available 6c potency of nux.v, with plain ethanol, you have to use the same type of ethanol which was used for its preperation. Simple basics.

Murthy
I am thoroughly familiar with the basics of research, and Roy has clearly not followed them (in the work that you cited). Again, if you weren't in such a hurry to dispute every sentence, you might make fewer mistakes. You might even learn something. Wouldn't that be amazing.
 
Did Dr.Roy say that he used quote marks? When the results you are getting are different from what he quoted, why didn't you pause and think about what could have made a difference?
In the text, the phrases are indeed in quotes. Obviously he didn't enter them that way into Google, because the numbers are completely wrong.
Heavens are not going to fall, wheher it is 8 million hits or 17 million hits.
You mean, 8 million vs. 32,300.

Hey, I didn't bring it up. Complain to Professor Roy.

Instead of trying to dispute every sentence, concentrate on the main issues.
We have.

Rampant speculation.
Inadequate controls.
No blinding.
No specifics of the solvents used.
Citations that don't support the claims being made.
A curious disconnect between the opening subject (the intermolecular structure of water) and the solvent used in one of the examples (ethanol).

Hmm. What did I miss?
 
Did Dr.Roy say that he used quote marks? {snip}
That is exactly what he wrote. Didn't you read that part?
Instead of trying to dispute every sentence, concentrate on the main issues.

Murthy
Again, if you weren't in such a hurry to dispute every sentence, you might make fewer mistakes. You might even learn something. Wouldn't that be amazing.
 
Did Dr.Roy say that he used quote marks?


The phrases have quote marks around them in the article. And from the context, he is implying that the number of hits found says something about the amount of information already available about the structure of liquid water. If the search strings do not have quotation marks around them, the searches will bring up all indexed pages that have the words in the string on them; many (if not most) will not be about "the structure of liquid water": they will just have the words somewhere on the page in unrelated sentences. Without the quotation marks the search will also, for example, bring up any page containing the sentence "liquid water has no structure". This is not what the authors of the paper were looking for, is it? At best, it indicates an incompetence in the use of search engines.
 
Quote marks ("") matter in a database search. Slow down in your hurry to dispute every sentence, you might make fewer mistakes.

quotation marks ("") also matter grammatically. you seem to forget that they are also a simple grammatical or stylistic tool. note in this connection that roy embedded the search phrase within a sentence, so use of the quotes can (and according to correct english usage) would be a grammatical indicator, not a part of the search string itself (note in this sense that the comma is also within the quotes, but certainly not a part of the search string):

17 million hits on Google for​
“structure of water,”​

also in the following phrase, a header, the quotes are clearly grammatical, enclosing the "term" in question:​

[FONT=TimesNewRoman,Bold]Deconstructing the terminological confusion around the term “structure of water”​

[FONT=TimesNewRoman,Bold]this is a simple matter - or so one would think. i suggest it should give all the brains around here pause, for how easily mistakes can slip into anyone's work, originator or critic.[/FONT]​

neil​
[/FONT]
 
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quotation marks ("") also matter grammatically. you seem to forget that they are also a simple grammatical or stylistic tool. note in this connection that roy embedded the search phrase within a sentence, so use of the quotes can (and according to correct english usage) would be a grammatical indicator, not a part of the search string itself (note in this sense that the comma is also within the quotes, but certainly not a part of the search string):

17 million hits on Google for​
“structure of water,”
also in the following phrase, a header, the quotes are clearly grammatical, enclosing the "term" in question:​
[FONT=TimesNewRoman,Bold]
Deconstructing the terminological confusion around the term “structure of water”
this is a simple matter - or so one would think. i suggest it should give all the brains around here pause, for how easily mistakes can slip into anyone's work, originator or critic.​


neil​
[/FONT]


Do you think that Roy wanted to look for pages containing the sentence "liquid water has no structure"? Look at the context.
 
[FONT=TimesNewRoman,Bold]this is a simple matter - or so one would think. i suggest it should give all the brains around here pause, for how easily mistakes can slip into anyone's work, originator or critic.[/FONT]
The problem is, if Roy didn't include the quote marks in the search, the results are completely irrelevant. The first page of results might be on topic, but just a few pages in you're getting hits on climatology, plumbing, and the design of wireless computer networks.

Minor point, but still...
 
The phrases have quote marks around them in the article. And from the context, he is implying that the number of hits found says something about the amount of information already available about the structure of liquid water. If the search strings do not have quotation marks around them, the searches will bring up all indexed pages that have the words in the string on them; many (if not most) will not be about "the structure of liquid water": they will just have the words somewhere on the page in unrelated sentences. Without the quotation marks the search will also, for example, bring up any page containing the sentence "liquid water has no structure". This is not what the authors of the paper were looking for, is it? At best, it indicates an incompetence in the use of search engines.

boldface may be correct; but it also reflects that in critiquing roy's paper, you have mis-read his copy (see my post immediately preceding). not only on grammatical grounds, either - apparently, the numbers are in closer agreement with roy if one uses the search phrase without the quotes. it may also be that roy was looking for as many citations as possible, that could reasonably be assumed to stand in some fairly direct relation to the subject of interest - a more charitable pov, if one were inclined to charity.

of course, the best approach to the problem would be to search both ways and to comb both resulting lists and evaluate the items one by one for inclusion in the final count, or to diligently anticipate that this sort of objection would be raised within some corner or other of the more-or-less academic community, and to discuss one's search strategy at length, at least in a footnote....

but, personally, i think it is difficult to anticipate all of this, and that in our partisanship we can expend too much energy on the matter. i still have not read the entire passages thoroughly, but from what i have read, roy makes his points articulately ... maybe that would be a better place to ground a disucssion of his search findings.

neil
 
Rampant speculation.
Inadequate controls.
No blinding.
No specifics of the solvents used.
Citations that don't support the claims being made.
A curious disconnect between the opening subject (the intermolecular structure of water) and the solvent used in one of the examples (ethanol).

Hmm. What did I miss?

This is the sort of analysis I am looking for, though the above is just the tip of the iceberg. Let us have little more depth on the technological issues. Think of more.

Murthy
 
it may also be that roy was looking for as many citations as possible, that could reasonably be assumed to stand in some fairly direct relation to the subject of interest - a more charitable pov, if one were inclined to charity.
If that's what he wanted, then he missed by a mile.

of course, the best approach to the problem would be to search both ways and to comb both resulting lists and evaluate the items one by one for inclusion in the final count, or to diligently anticipate that this sort of objection would be raised within some corner or other of the more-or-less academic community, and to discuss one's search strategy at length, at least in a footnote....
You don't have to do anything of the sort. You just have to include the quotes, just as he did in the paper.

It is a minor point, but Roy raises it twice as though it had some special relevance, and it's completely and utterly wrong.
 
An understanding of the structure of liquid solutions is required ....
An understanding of the structure of liquid solutions is required for understanding. interactions in a broad range of biological systems. Water is a ...


that is from page 14 of my own google search - i stopped at page 27 with much the same kind of content. i did not go to page katrillion or whatever. without having scrutinzed all 170,000,000 of returned citations, i will concede that roy's search was less than ideally structured, and that he missed a decimal point in counting the listed results. otoh, you guys missed the comma. either way, what does this exactly prove?
 
Hmmm, I actually started to compose the post below just after PixyMisa posted his 11.40 post (quoted), in between doing some actual work. By the time I got it up, much of my musings seem to have been covered, especially by Mojo.

Perhaps they were making the same mistake as Kumar ("Kayvee" to you, bvw12).


A day late and a dollar short, sorry. But here it is.

Introduction, first sentence:

Nope. Try it: The first phrase returns 32,300 hits; the second, 224,000.


I looked at the PowerPoint slides. They're terrible! It's difficult to imagine how any serious academic can put anything out with presentation this bad. It looks as if Kumar's Pakistani homoeopath friends did the visual aids! Still, I found something out. In an earlier thread on this topic, it was claimed that Roy was a Nobel laureate. This I found somewhat surprising. However, I note from the initial slides that there is no mention of such an award in his credentials list. There is however a throwaway remark that three Nobel prizes have been awarded for work on metallic sols. To whom and for what discoveries, not stated. OK, that's that cleared up. Why can't homoeopathy proponents learn to read?

So then I looked at the paper itself, out of sheer disbelief that any serious academic work could possibly incorporate what we dubbed "argument by Googlefight" when Kumar started doing it. (I think Kumar right (without any inverted commas) got more returns than Kumar wrong, so that proved he was right, or something.) [OK, Mojo, ten extra points for finding the post, I see it was Kumar is intelligant and Kumar is idiot.]

But it's true! The number of returns on a Google search is actually quoted by Roy et al. as if it had some meaning! I scarcely believe it.

Short digression. I recall Kumar's Googlefight argument when we were trying to explain to him the function of the inverted commas. I'll skip over the question about whether the crow should drink the water in the pot, which implied that Kumar thought the Internet could magically supply the answer to whether or not the water in one particular pot was safe to drink! His other example was about whether or not grapes were sweet. He contended that since the phrase - are grapes sweat - with no inverted commas, got him a lot of returns, and "are grapes sweat" got him none, then the former was the better way to ask the question. It was pointed out to him that exactly none of the links provided by the first search actually answered the question (because he was persistently mis-spelling "sweet"), so it was in fact useless. However if he could bring himself to spell the word correctly, a search on "are grapes sweet", with the inverted commas, while producing very few returns, actually answered the question. This all fell on deaf ears as far as I remember. He continued to assert that a search without inverted commas was superior because it produced more links.

So is that what's going on here? I get 24,300,000 returns for structure of liquid water (no inverted commas) and 170,000,000 for structure of water. However I get 32,200 for "structure of liquid water" and 223,000 for "structure of water" - much the same as PixyMisa got.

Huh, neither of these really figures.

The wording of the paper is very odd.

The “structure of liquid water” receives some 8 million hits on Google and the “structure of water” over twice as many. Any contribution that can be made to this vast body of knowledge is sure to be marginal. This paper does not report any such incremental advance with ultraprecise measurements about the structure of oligomers, femtosecond spectroscopy of bond breakage or phase transitions in glassy water. Instead, it examines the literature to establish only one proposition, that pure, thermodynamically stable or metastble liquid water can have more than one 3-D condensed matter structure. While we assemble here various sets of relevant data and lines of argumentation, by a coincidence, at the same time as this paper was first presented orally (April 2004), Kawamoto et al. published their paper providing the experimental proof of this assertion [1, 2].


I'm having increasing difficulty reconciling this nonsense with the concept that any of the people responsible are or have ever been serious academics.

First, the terminology is strange to me. To "receive a hit" to me seems to be talking about a web site getting a certain number of visitors. Yet they seem to be using this form of words to describe the number of links returned in a Google search. But are they? The numbers bear no relation to the actual number of links returned when one actually does these searches, either with or without the inverted commas. I wondered if they were meaning this was the number of times such a search had been performed on Google (over what time period?), but that makes no sense either.

Second, they are equating links returned on a Google search with a "vast body of knowledge". I hardly have to point out how imbecilic that concept is. Any serious scrutineer of any scientific paper would kill that assertion stone dead. Which rather illustrates the quality of the scrutineering, if any.

Third, they seem to be saying that the paper is purely theoretical, and presents no experimental data. Fine. There's a reason I should read this?

Fourth, there is a mention of someone having published some actual experimental data. It seems to be to "Kawamoto et al. [1, 2]. However, when we look at the reference list, references 1 and 2 are:
[FONT=TimesNewRoman,Italic]1. Roy R (2004) A contemporary materials science view of the structure of water. Symposium on Living Systems/Materials Research, Boston, MA, Nov. 28, 2004[/FONT]

[FONT=TimesNewRoman,Italic]2. Katayama S et al. (2004) Science 306:848[/FONT]


It took a little bit of thought to realise that in fact the reference citation is simply completely screwed up. First, reference 1 is not to the experimental work, but to Roy's verbal presentation of his own theories, which happened at about the same time as the experimental work was published. Instead of printing
by a coincidence, at the same time as this paper was first presented orally (April 2004), Kawamoto et al. published their paper providing the experimental proof of this assertion [1, 2].


what should have been printed is
by a coincidence, at the same time as this paper was first presented orally (April 2004) [1], Kawamoto Katayama et al. published their paper providing the experimental proof of this assertion [2].


Oh yea, and "metastble " is obviously a mis-spelling.

This again argues for a totally amateur setup. Any competent scientific editor would have fixed the [1] having been put in the wrong place, and the name of the author of paper [2] having been completely mangled, and the mis-spelling.

I'm sorry, but when something is presented in such a cackhanded and unprofessional way, then why should I take anything in the paper seriously? These people are supposed to be serious academics, and serious academics know about the importance of presenting your work professionally, but their presentation - well, it has all the hallmarks of amateurish quackery.

By the authors' own admission, the paper is purely theoretical fantasising, apparently along the same lines as Lionel Milgrom's quantum logorrhoea. If they can't even present their work in a professional format (Milgrom at least manages to do that!), what incentive is there even to read further?

This does make me wonder. Is Professor Roy real? If there is such a person, and he did publish a good paper in 1956, is it actually the same person writing now? Or could this all just be a complicated Internet hoax? How to find out?

However, there's still Kawamoto (or is it Katayama?). Science 306:848.

Macroscopic Separation of Dense Fluid Phase and Liquid Phase of Phosphorus

Yoshinori Katayama,1* Yasuhiro Inamura,1 Takeshi Mizutani,1 Masaaki Yamakata,2 Wataru Utsumi,1 Osamu Shimomura1

Structural transformation between a dense molecular fluid and a polymeric liquid of phosphorus that occurred at about 1 gigapascal and 1000°C was investigated by in situ x-ray radiography. When the low-pressure fluid was compressed, dark and round objects appeared in the radiograph. X-ray diffraction measurements confirmed that these objects were the highpressure liquid. The drops grew and eventually filled the sample space. Decompressing caused the reverse process. The macroscopic phase separation supported the existence of a first-order phase transition between two stable disordered phases besides the liquid-gas transition. X-ray absorption measurements revealed that the change in density at the transition corresponds to about 40% of the density of the high-pressure liquid.

And so on.


Excuse, me, it's not really my subject, but does this paper have anything at all to do with the price of fish? I was wondering why it was Roy and not Kawamoto Katayama the homoeopaths were trumpeting, but it seems as if only Roy in the whole world believes this work has any bearing on homoeopathy - even the woos can see that citing the Science paper is completely irrelevant.

Look, this Roy stuff is so full of implausibilities even before you get as far as finding out what he's actually saying that I really don't think I'll bother. My main question now goes straight back to, does Rustum Roy actually exist at all, and if there is indeed such a person with these qualifications who published a seminal paper over 50 years ago, is it actually he who is responsible for the present unprofessional and implausible presentation. Or could it just possibly be a complete hoax?

Rolfe.
 
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