I saw that show. The astronauts only wore the black rubber gloves during liftoff. Those gloves were never worn in the vacuum of space. They needed the dexterity of the rubber gloves to flip switches and such. The gloves that they wore on the moon were much too cumbersome to wear in the capsule.
Here's a photo of the black rubber ones...
http://media.photobucket.com/image/apollo astronauts boarding the saturn v/loaloauk/c-5.jpg
Steve S
Actually what you see in that photo is the internal pressure suit glove. Here's a better image from my website:
See those big bulky knuckles? They are called constant volume joints, and when you bend your hands, these joints, as the name implies, keep the same volume throughout the movement. It is the change in volume of the joints in ordinary gloves that make them hard to bend, with the volume the same in these gloves, they are more flexible when pressurised. The gloves are far from just simple rubber gloves, they are in fact highly engineered peices of equipment.
They are also the gloves that were worn on the lunar surface. About now someone is thinking, "But I've seen photos of the ones they had on on the lunar surface and they were white, how can they be the same gloves?" The answer is actually pretty simple. The white gloves are beta cloth over-gloves that were worn to protect the black pressure suit gloves which were underneath, hence the white gloves in the photos. This also explains the oft misunderstand occurance where Armstrong and Aldrin opened the LM door and threw out their PLSS, gloves and boots before launch from the lunar surface. Many have been confused by that, after all how could they still be pressurised without gloves and boots right? The answer, they threw out the white over-gloves and boots while still wearing the internal pressure ones (which we see in the photo above and quite obviously aren't on the lunar surface.).
Now the program spoken of was
The Truth Behind the Moon Landings done by the Discovery Channel and Zig Zag Productions. The man that did the vaccum experiment was the late
Ralph René. The biggest flaw in his presentation where that he used a standard linesman glove, not a properly engineered Apollo glove, in fact he claimed that there was no special engineering in the Apollo glove, which as I have shown above was totally wrong. The other major flaw was that he evacuated the case meaning that there was a 14.6 psi pressure difference between the inside of the glove and the inside of the case. The Apollo gloves were only pressurised to 3.8 psi, just 26% the pressure difference that Ralph was using.
Jay Windley was also on the show (he did all the imagary with the Hassleblad out in the desert) however the producers unfortunately didn't tell him what they had discussed with Ralph so he wasn't able to rebut it on the show itself.
Edit to Add: I should also add that even with the CVJs and lower pressure, the gloves were not exactly easy to use, in fact the Astronauts themselves commented on how tiring it was, for instance from the Apollo 17 ALSJ:
124:14:23 Cernan: Okay. Give me a chance to turn around and look. Okay. White dots are out; all the white dots. Okay, they're all out here. Boy, does this feel good to get soft suits. Oh, my hands.
[Cernan - "Your hands just get so tired and sore, both from the work of squeezing your gloves around things all day and from the constant chafing. I wound up with blisters all over my hands, particularly between the thumb and the forefinger."]