Malerin, I'll go over it for you one more time.
1. If physicalism (materialism, reductionism, whatever) is true, all mental states are reducible to brain states.
Correct.
2. If physicalism is true, complete knowledge of brain states results in complete knowledge of mental states.
Correct.
3. If physicalism is true, then Mary has complete knowledge of the mental states associated with perceiving red when Mary has complete knowledge of the brain states associated with perceiving red.
Correct.
4. Mary has complete knowledge of the brain states associated with perceiving red.
So stipulated.
5. Mary perceives red for the first time.
There is a problem here, but I'll leave it for the moment, because there's a much worse problem in the next step.
6. Mary learns of a new mental state associated with perceving red.
No.
Mary does not learn anything new. She already knows exactly what it is like to perceive red. You said so.
There is an inconsistency here, but it is in the argument itself, not in the position of materialism.
If materialism is true, Mary does not learn anything new about the perception of colour when she leaves the monochomatic room.
It's very very simple, so I'll say it again:
If materialism is true, Mary does already knows exactly what the experience of seeing red is like before she leaves the room.
This is stipulated by the argument. It's a physical process of colour perception. Mary knows everything there is to know about the physical process of colour perception. Therefore she already knows what it is like to see the colour red.
The problem with premise 5 is that in a very important sense, Mary has already perceived red before she physically sees it for the first time. She already has access to the mental state of seeing red for the first time before she physically sees it for the first time.
If you accept the premises that mental states are physical states, and that Mary knows everything there is to know about the physical process of colour perception, then it is an inescable conclusion that Mary already knows what it
feels like to see colour. "Feels like" is a mental state, which is a physical state, which it is stipulated that Mary already knows.
If you don't accept those premises (for the sake of argument, at least), then you can't use modus tollens.
And if you don't accept that, then you don't understand the basic laws of logic, and you're wrong by default.