According to a friend of a friend an engagement fell apart once when the woman found out the diamond in her ring was synthetic and not mined out of the ground. Her fiance was able to do this because he had a friend that worked with synthetic diamonds so he had a jeweler put it in. He didn't lie about it either he just didn't say anything to see if she would notice. Then when he did break the news to her she freaked out and claimed he didn't actually love her.
Or so the story went.
Unlikely. A synthetic diamond of sufficient size and quality to be cut and mounted as a gem would cost rather more than a precut natural stone of the same size. More trouble than it would be worth.