I too am unschooled in this.
And I owe all you good people on this thread an apology. I must have driven Sol Invictus, Ben m, and Ziggurat to despair, by not acknowledging the fact that
if the charge-carrier is accelerated by the junction to achieve the extra energy qV, the conservation of energy is violated. Furthermore, the defining characteristic of a superconducting charge-carrier is that it can
NEVER be accelerated.
I derived the actual origin of this extra energy 4 years ago; and it is more subtle than being the result of acceleration. But before explaining this aspect (hopefully correctly this time around) I must first explain how it could happen that I could have been as stubborn as a donkey in my postings on this thread. To understand this, you must know a bit more about me and the history of my first engagement with the theory of a Josephson junction.
Unfortunately I was born with an affliction: My long term memory is severely impaired. I can, for example, do a mathematical derivation not realizing that I have already done the same derivation 2 weeks prior. I am like a computer with an excellent CPU but only a few kilobytes of memory. Fortunately I am not yet as bad as the guy who visited his doctor and told him: " Doctor I cannot remember a thing". The doctor inquired: "For how long has this been so?" And the guy responded: "For how long has what been so?"
When I realized 7 years ago that superconduction occurs by barrier-jumping of electron-orbitals, I was still firmly convinced that these orbitals must be doubly-charged or else they will not all have the same lowest energy. In my first book I thus modeled all the superconductors as having boson charge-carriers. For the ceramics, these charge carriers could be modeled as "covalent-bonds" which form between the crystallographic layers. The calculations fitted the data for both the low temperature metals, and the ceramics like YBCO, extremely well indeed. I had no issue with Josephson's model of tunneling at that point and thus argued that his model dovetails with my mechanism.
After having written and published the book (unfortunately using a VERY expensive publisher) I proceeded to analyse other published data on superconduction using my mechanism of barrier-jumping-bosons. Only then disaster struck: I found that when I calculated a flux quantum using my mechanism, it must be smaller by a factor 2 than the flux quanta which have been measured; where this factor 2 came from Heisenberg's relationship between energy and time. The only way to get the same value as experimentally found, was to assume that the charge-carriers are not doubly charged, but only singly charged.
Only then I turned my mind to Josephson tunneling. The dilemma was that if the charge-carriers are singly charged as indicated by my model when calculating the value of a flux quantum, and tunneling occurs while there is a voltage V over a Josephson junction, the radiation should only have an energy eV and not 2eV as is measured. Where does the extra energy eV comes from? At one point I reasoned that it must come from the vacuum and was excited that I have found a way to solve the world's energy problems for once and for all. Nonetheless I had sleepless nights until I finally realized that this extra energy must be added to the orbital in order for the singly-charged orbital to scale the junctio,
without being accelerated. The fact that the orbital must obtain this energy in order to jump the Josephson junction stuck in my limited long-term memory without the fact that it is not generated by acceleration but rather to avoid acceleration. Only last night after searching myself to death did I find my original calculations.
As I have posted already, a superconductor must be a perfect dielectric or else an applied electric field will not be cancelled within such a material; and since the field is cancelled while a current is flowing a superconductor cannot be a conductor, since a conductor cannot cancel an applied electric field while a current is flowing. Thus a superconducting phase must in essence be an array of localized orbitals, which cancels the applied electric field by polarization. Thus the total energy of the applied electric field is stored within the orbitals. It is like a capacitor with a perfect dielectric which stores all the applied electric field-energy so that the voltage over the capacitor plates is completely cancelled.
Here I must first give a bit more detail before proceeding further to the Josephson junction: Obviously,
all the applied electric-field energy can only be stored by polarization of the charge carriers when they form a minimum energy state at absolute zero. Above this temperature there are in addition to the localized superconducting charge-carriers, also free charge-carriers, but one can include them in the model without changing what I am going to state below by assuming that the superconductor is actually at absolute zero temperature: The equations and interpretation of the equations only become a bit more complicated when discussing the situation for a temperature above absolute zero.
Thus not to make the explanation more complicated, we will assume that the superconductor is at absolute zero temperature and that the applied electric field energy is totally absorbed by the internal polarization of these localized states; and that any increase in the applied electric field will also be absorbed by further polarization which increases the energies of the orbitals further. Although this increases their energies to be larger than it is without an electric-field, they can still barrier-jump while also transferring this extra internal energy: This ensures that they do not accelerate while jumping; since there is no electric-field present which can accelerate them during this movement. However, when this polarization energy becomes too large to absorb, superconduction becomes impossible: This is one of the reasons why a superconductor has a critical current.
Now back to the Josephson junction. Without an applied electric field over the junction, the orbitals barrier jump it as if it is not there, since it is thin enough to allow this to happen. With the electric field the orbital can only jump without encountering this electric-field by increasing its internal energy by qV. Thus this is the extra potential energy it has when it reaches the other side; and which it must have to move without acceleration as the charge-carriers within a superconductor must move or else they do not form a superconducting state. Since there is plenty of stored electric-field energy within a superconductor, this added energy is extracted from this stored energy and therefore there is no violation of the conservation of energy.
I apologize again for my bad long-term memory. It has embarrassed me all my life. Oh why an I not be like Stephen Hawking who can do complicated mathematics totally within his cranium? I envy him!
I just realized that I have also been unclear about this aspect in my recent book, and must therefore issue a more detailed explanation. This will be done on my website and also sent to those persons who have already bought the book and those who are buying the rest of the present copies I have. The new printing will be changed. I will have to also change the cover since the Vatican asked me not to use the image of God that is on the ceiling of the Sistine Chapel.