johanfprins
Graduate Poster
- Joined
- Dec 1, 2010
- Messages
- 1,015
I have NEVER said that you can get it by just using the classical potential on its own. This is the type of mistake that only you, Sol and Ben have made consistently on this thread. You are the ones who claim that you can apply classical electrodynamics to a state that has been obtained by solving the Schroedinger equation.No, actually, you cannot get that number by calculating the classical potential between an electron and a proton.
What I say is that you use the classical potential between the electron and the proton as input to the Schroedinger equation. After the solution it has no direct meaning anymore; as you Sol and Ben want to argue.
Of course you have done it since you are believing in doing Voodoo calculations.If you try, you will not get -13.6 eV, you will get -27.2 eV. I've done it.
Exactly! I am not soYou clearly haven't, and don't actually know how to despite claiming you can.
stupid to calculate irrelevant physics: I leave that to you Sol and Ben.
The Lorentz transformation at low speeds applies. So how can they be "non-relativistic"?Sure, you can do that, EXACTLY like you can do that in Newtonian mechanics, because both Newtonian mechanics and the Schrodinger equation are explicitly non-relativistic.
You have calculated the expectation value of the "potential energy" <V(x)> and you claim that you will get the same expectation value using ANY reference potential? I can assure you that <V(x)+K> will not be the same as <v(x)>. But maybe it is just that I cannot do the calculation. I will thus appreciate it if you can prove to me that <V(x)> is equal to <V(x)+K>.I don't agree. The Schrodinger equation is explicitly non-relativistic. And mathematically, it's provable that the choice of reference potentials makes ZERO difference to any expectation value calculation.
Different reference potentials will give different values for the "expectation value" of the potential; and this will give you different solutions to the total energy of the electron-wave. But maybe it is just I who cannot do the calculation. Can you prove to us that for different reference potentials you will get the same expectation value for the potential energy? I suppose i am not as good as you when it comes to doing this mathematics.Not that it matters, since this also means we're free to pick the reference potential equal to the vacuum level.
Really? Please calculate k using a deltafunction (delta)(k-kp) around kp. Do you get zero or do you get kp? And then calculate <(k-kp)2> and show that it is larger than kp.No, johan, this is most definitely NOT a possibility. It's a mathematical impossibility. The only possible k-space distribution which will give <k2>=0 is a delta function at zero, but that also has <k>=0.
But as you maintain: Maybe I am just too stupid to do the calculation correctly. So please correct me.
Not so for a travelling, coherent wave which has only ONE unique value for k. Its represenation in k-space is the delta function and in this case <(k-kp)2> is according to my mathematics zero. But of course I am dumb and stupid when it comes to these calculations: Please help me from my stupidity and post the correct calculation here so that I can learn at the feet of the master.In fact, it's an absolute MATHEMATICAL requirement that <k2> >= <k>2. That's not even peculiar to k space, that's true of any distribution. This is a really basic and obvious mathematical fact, and you screwed it up completely.
It still cannot be kinetic energy since kinetic energy, if it exists must be given by <p>2/2m. But for a stationary wave <p>=0, thus there cannot be any kinetic energy. Or is it again that I am just stupid?I don't care if you don't want to call it kinetic energy. <p2>/2m is still part of the total energy of the wave function. Call it whatever you like, it's still a necessary component.
It is not a superposition of two weave packets. Within its own inertial refrence frame it is a localised stationary wave, or else it will violate Galileo's inertia. When you are within another reference frame, this localised stationary wave (within its own reference frame) will move at a speed v past you. If you now apply the Lorentz transformation you will find that this localised wave is now longer and that along its length the "time changes": i.e. the phase angle of the wave is now different with position along the wave. For this reason the wave is now a running wave with a de Broglie wave length. ONLY NOW there is a momentum and a de Broglie wave length: And only now does the wave have kinetic energy. But when the wave is not moving relative to you, it does not have a de Broglie wavelength since it does not have a momentum at all: And therefore there is also no component of its energy that is kinetic energy.Furthermore, your logic is quite obviously absurd. For instance, if a free particle wave function is a superposition of a left-moving wave packet and a right-moving wave packet, it's not a free particle at all. It's quite clearly moving. It has kinetic energy, doesn't it?
Correct: No momentum - no kinetic energy. It has been like this since the time Newton postulated his laws and no physics which came afterwards (including quantum mechanics) has, and I believe can, change this fact.And yet, <p> = 0.
Well then why do YOU not do the correct derivations and post them here.And once again, you prove you cannot do math.
There is a very simple book called Teach Yourself Calculus. Try an read it and you will find that one of the fundamental laws of calculus is that you can write that for two functions y and x who both depend on t that (d/dx)y= (d/dt)y*(d/dx)t.If <F>=(d/dt)<p>, then <F> ds = (d/dt)<p>*ds. And that is NOT the same thing as (ds/dt)*d<p>.
Only when the wave is stationary and the classical potential does not change with time. When the wave moves, the expectation values do change with time, just as Ehrenfest has proved.Furthermore, it doesn't even make sense in either form, since expectation values are not functions of position.
I did not fight tooth and nail against using Ehrenfest's theorem. I do fight tooth and nail when you Sol and Ben use correct theorems to argue Voodoo physics: As is your custom.There's also the additional irony that you have previously fought tooth and nail against using Ehrenfest's theorem in this very thread.
What potential do you insert into the Schroedinger equation before solving it, if not the classical potential? Plesae solve the hydrogen atom for me without using e2/r.And yet, you just said in this very post that you could get the energy from the classical potential.
You are the one who is inconsistent and who does not even know that (d/dt)y*ds can be written as (d/dt)s*dy. And you want to tell me that I cannot handle calculus?Oh, but then, that's me expecting consistency from you, and that's wrong of me.
Where have I stated this? What I keep on stating is that the Schroedinger equation is incorrectly interpreted in terms of paranormal concepts like "wave-particle duality" and "complementarity" which lead to the oxymoron conclusion that a standing harmonic wave can have kinetic energy. No stationary harmonic wave can ever have kinetic energy: Only a harmonic wave that moves relative to an inertial reference frame has kinetic energy within the reference frame relative to which it is moving.Apparently everything to do with the Schrodinger equation is nonsense.
Why not? It gives results: But what I really demand is that you should interpret these results correctly so that you do not make the paranormal conclusion that a stationary entity has kinetic energy.And yet, you demanded we use it.
YOU claim that a stationary entity has kinetic energy and then has the arrogance to accuse ME of inconsistency?I know you've thrown the very idea of consistency to the wind,
Yes I agree: You, Sol and Ben have long ago crossed over these limits into paranormal never-never land.but there are limits,
Can you give me an experiment where either one of these terms has been measured separately from the other?now said both terms in <H> = <p2>/2m + <V> have no meaning.
I have given you the meaning. So here I will give it again: For a time independent potential well measured from the vacuum level, the Schroedinger equation gives fairly accurate solutions of the energy-intervals of standing waves as measured from the vacuum level. These energy-intervals are reductions in the mass-energy of the waves, so that their total energies (which are purely mass energies) are all below the rest mass energy.
It only seems as if one can model the reduction of mass by using parameters which remind one of potential and kinetic energy. This is an artifact because the Schroedinger equation uses rest mass as an input, and therefore it seems to be an eigenvalue equation of the Hamiltonian of a "particle" with mass m. It is this mass as input that is misleading since a differential wave equation that models matter should not have mass as input: Its solutions must be mass energy m, which will have a kinetic energy component ONLY when m>me; BUT NOT when m<me as you claim that one can have have for bound electrons around a nucleus.
