Tetraethyl lead was primarily used as an antiknock property, if I can believe anything I've ever read or been taught about it. For example,
this patent from 1939 specifically says that tetraethyl lead is an anti-knock additive, and
this biography references plenty of sources from the 10's and 20's, and claims tetraethyl lead was the result of years of research into anti-knock additives. It also claims that Ethyl was the name for a small amount of tetraethyl lead that was sold to consumers, so they could add it by hand, as well as the name of the company that marketed and sold leaded gasoline.
Indeed,
Tetraethyl lead was both an anti knock AND valve lubricating additive. Not necessarily in the valve guide department, tho. It seemed to make a coating on the hi-temp valve and seat area, helping to transfer heat away from the valve edges,to the cylinder head.
When tetraethyl was removed from the fuels, the valve seats(which were ground into the cylinder head-no such thing as valve seat inserts for production engines), and valves would burn up, erode?-losing their seal. Manufacturers responded with the hardened seat inserts, to be installed into the burned area, and ungrindable valves replaced.
*snip* originally posted by Schneibster:
No. In older engine designs, the valve guides in the cylinder heads required lubrication. Tetraethyl lead was added to the gasoline to provide this lubrication. Originally, there was a separate, more expensive grade of gas, known colloquially as "ethyl," that people would run a tank of every eight or ten tanks to provide this lubrication; then they eliminated this, putting it in all grades, in lesser amounts, because people would forget and damage their cylinder heads. But lead is known to be a poison, and also interferes with the action of the catalyst beads in a catalytic converter,
so they had to make cars that could burn unleaded gasoline; to do this, they used bronze valve guides, because bronze is self-lubricating on steel valve stems. Today, you can't get heads that don't have bronze valve guides and require leaded gas; most even of the cars that originally required leaded gasoline have had their heads replaced with ones that can burn unleaded.
end of quote. underline mine.
Mixed information, some not even wrong.
Updating a former leaded engine consists of cutting the valve insert pockets into the cylinder head, installing seat inserts, reground or new valves. Valve guides probably would be changed, if worn, or knurled, and reamed to fit. Certainly the valve stem seals would be replaced. (these are the little seals which control the lubricating oil quantities on the stems and guides.)
Yes Virginia, it's true- OIL lubricates the guides and stems!) (Where lubrication is used. See below.)
As far as the wonder qualities of bronze guides-some engines today have them. Some do NOT, using cast iron guides .Irregardless, both seem to work equally well.
Some engines have alloy(aluminum based) cylinder heads, some are cast iron. Same concerning engine blocks.
Trick with alloy heads & blocks, is the coefficient of expansion: it is greater than the steel , iron, bronze ,parts, and if parts are not fitted correctly-the parts loosen , with disastrous results. Also the reason today's alloy engines are so susceptible to cylinder head leaks from overheat operating condition.
Engineers work this out in advance-hopefully!Well, maybe not.
Consider this- about 1950, your run-of-the-mill Chevy 6 OHV engine had NO valve train lubrication(it was an option), nor did it come with an oil filter(option). Those omniscient GM engineers just tapped a gallery, strapped the oil line to the valve cover, with penetrations as req'd, to oil the valve operating mechanism. The filter was strapped to the side of the engine with a stamped steel bracket, tapped off a gallery, and drained to the crankcase.(by-pass, not full flow)Oh yeah-you fished the element out of the canister. Some elements had little wire bails by which to grab them .(messy)
Cool, huh? Autos which made 100K miles were
rare!
I still remember my dad telling me "What's good for GM, is good for America!"