I don't know, maybe I am wrong, but I completely fail to see what the host's intention have to do with the outcome - he has to open a second door
Unfortunately, a lot of times this stipulation is not made. You are only told that 1) he does open a door, and 2) there is a goat behind it. You are not told that he always does this when this game is played, nor that when he does it, that he knows that he will reveal a goat.
and it is a given that the second door will not contain the prize. I fail to see how what is in the host's mind has any bearing on the statistics.
As noted, you are making an assertion that is not always part of the equation: that he always does this and that the door WILL NOT contain the prize. If that is part of the problem, fine. But it is not always the case. What is often (usually?) given is that a) he HAS opened the door (nothing about it being always) and that b) it DID contain a goat (not that it always contains a goat).
If he doesn't always open a door, then you do not know that he only opened it because you guessed right. Therefore, you need to know his motivation.
Second, whether he knows which is the right door or not also matters. If he does not, and is only guessing, then there is a 1/3 chance that he could reveal one with the car. The problem with that is that, as pointed out above, he has just ruined your chance of winning because it means that you did not select the car initially. This is a case where you would have been wise to switch, but because he revealed the car accidentally, you aren't able to make that switch. Thus, it hurts your chances of winning if you switch.
You can convince yourself of this by using cards (ok, I did it with excel, but it becomes pretty obvious pretty quick - if the second door is selected randomly, then the odds of winning in those events when the car is not revealed is 50/50)
So you need to know 2 things: 1) that he is not acting maliciously, and 2) that he knows what he is doing and only reveals a losing door. If you can establish those two things, than you can assuredly say the odds are 2/3.
ETA: Billy, below you will see the problem as presented in the first post of this thread
Monty presents 3 doors; behind one is a car, and behind the other two are goats. You pick a door. But before Monty opens that door, he reveals behind another door that there is a goat. He then gives you the opportunity to switch your choice. What is the probability that you will get the car by switching, or by staying?
You can see that the assumptions you have made (he always does this, and he always reveals a goat) are not explicitly noted. This is a common occurence.