Just for kicks, I started to try to calculate this (using my now 10-year-old college chemistry skills and somewhat older textbook), and gave up when the numbers started getting ridiculous.
Now, this is very handwavy, but if you think about it, you'd need enough methane to have made a 1% concentration on a _LARGE_ area.
- stormy conditions indicate that there was massive airflow in the region
- at even 1000 feet, the methane would have dispersed a great deal
- it there was enough methane to trigger a 1% concentration at that height, it _would_ have been noticed - the human nose can detect methane at concentrations _FAR_ below that.
(First post, by the way.)