I'm not going to prove or disprove anything by talking about how CO2 acts to change the heat balance of the planet. That would be megalomania. It seems some people actually do argue that CO2 can't have much effect, that it can't physically do much, but I tend to ignore such arguments, what would be the point?
There is a demonstration of how a little bit of CO2 can have a big effect here -
http://www.dailykos.com/story/2010/03/08/843974/-Can-CO2-warm-the-Earth-if-it-s-only-0-04-of-the-air
I find that quite effective at showing how a little can have a big effect. I want to know what the effect is. Wikipedia seems to be quite wrong, and it's surprising to see how difficult an answer to these questions actually is.
If CO2 does warm the air itself, that is two mechanisms that cause warming. And certainly a different story than it just re-radiates IR back towards the surface.