Energy, Entropy, and the Collapse of WTC7
If a person holding a brick of mass m releases it, it will fall to the ground. Why? The force of gravity describes
how it falls (central forces are symmetrical with respect to time-reversal), by
why it falls is due to the Second Law of Thermodynamics, namely the whether the entropy increases. The change in entropy for the falling brick is ΔS = KE
brick/T, where KE
brick is the brick’s kinetic energy the moment before it hits the ground, and T is temperature. We can apply this concept to WTC7 to test whether the NIST’s explanation for the collapse is plausible. We do not need to know the causal relationship between the specific chain of events that took place internally during the collapse, because of the fact that the maximum work available to a system is the reversible work [1]. Furthermore, when the reversible work is maximized, the total change in entropy of the system is zero, and this allows us to relate the change in entropy associated with the initiating mechanism, to the change in entropy associated with the final collapse mechanism, provided both mechanisms can be clearly identified. Fortunately, the NIST chose an initiating mechanism – heating a girder – for which the “initial” change in entropy is easy to calculate. Also, the “free-fall” portion of the collapse provides a conveniently identifiable unit of measure to calculate the “final” change in entropy associated with the latter mechanism.
The final change in entropy ΔS
f associated with the WTC7’s 2.25s of free fall is, similar to the brick example, just the change in kinetic energy divided by temperature during the NIST's phase 2:
ΔSf = (KEupper section)/T = ½ * M/T * (vf² - vi²)
This is the amount of energy that is transformed into internal energy and transferred as heat into the surroundings.
Using dimensions from the NIST [2] and the trapezoid formula, we know that the area of floor plan of WTC7 is A = 3460 m
2, and the height is h
total = 186 m.
We can estimate the mass density of WTC7 to be roughly equal to that of the Twin Towers, as well as modern highrise buidings [3], ρ = 168.6 kg/m
3, with the number of storeys = 35 (floors 13 through 47).
So the mass of the upper part of building is estimated to be M = 8.08E+07 kg.
The 2.25 sec of “free fall” (the NIST's phase 2) began with an initial velocity of v
i ~8ft/s = 2.4 m/s, and ended with a final velocity of v
f ~80ft/s = 24.4 m/s [4], and even include a factor 0.95 to allow a 5% deviation from pure free fall acceleration.
The kinetic energy of upper block during the 2.25s “free fall” phase is then
ΔSf = (KEupper section)/T = 7.17E+07 J/K
Now for the initial change in entropy, ΔS
i.
The change in entropy due to an addition of heat is
dS = dQ / T = (1/T) m * csp * dT
And the total change in entropy due to fires heating the girder from T
1 to T
2 is:
ΔS
i = integrate (dS ) from T
1 to T
2 = m * c
sp * ln(T
2/T
1).
where m = mass of girder, c
sp = specific heat of steel.
The mass of the girder can be found from the volume and density. The cross-sectional area of a typical WTC7 girder is A = 38.3 in
2 = 0.0247 m
2 [5], and the length of girder is l = 15.8 m [6].
Given the density of steel, 7833 kg/m
3, the mass of the girder is about m = 3058 kg.
The c
sp = 550 J/kg K for constant specific heat (for T < 600°C) [7]. T
1 = 300 K, T
2 = 750 °F = 400 °C = 672 K
ΔSi = m * csp * ln(T2/T1) = 1.36E+06 J/K
So, comparing the change in entropy associated with the initial and final mechanisms, the difference is:
ΔStotal = ΔSf - ΔSi = +7.03E+07 J/K
This quantity should at most equal zero because the entropy of a system cannot be maximized more than the maximum available to the system. Therefore an additional source of energy had to have been present in order to deliver this extra amount of work to the system. In the language of thermodynamic potentials, the collapse process is not spontaneous, WTC7 is stable subjected to the thermal expansion, and the NIST’s explanation appears to violate the Second Law of Thermodynamics.
As we can see from this simple analysis [8] the thermal expansion of a girder is insufficient to cause the WTC7 to spontaneously collapse. We could extend this treatment to include additional beams and columns that may have been subjected to the heat from fires, and therefore somehow contribute to the collapse. However, the result would be the same because this exta amount of heat required to cause a change in entropy sufficient for collapse is equivalent to the amount required to raise two such girders to over 1400 °C. This is not possible from fires, although, coincidentally, it is consistent with the collapse mechanism of controlled demolition – the only hypothesis that can account for all the observable features. This is understandable, after all, because incendiaries and explosives are nothing more than a massive increase in entropy, which, if introduced to the system, would allow the collapse to proceed spontaneously.
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References
[1] H. Callen, Thermodynamics and an Introduction to Thermostatistics, pg 103
[2] NCSTAR1A - Final Report of Collapse of WTC7, pg 5
[3] Gregory Urich, "Analysis of the Mass and Potential Energy of World Trade Center Tower 1", pg. 25
[4] NCSTAR1A The Final Report on WTC7, pg 46
[5] NIST NCSTAR 1-9 Vol1 Draft for Public Comment, page 344
[6] Kevin Ryan, "The NIST WTC 7 Report: Bush Science reaches its peak",
[7] J.A. Purkiss, Fire Safety Engineering: Design of Structures, pg. 79
The present analysis uses the temperature-dependent specific heat of steel
csp(T) = c0 + c1 * T + c2 * T2 + c3 * T3 [J/kg K], where
c0 = -191.5 J/kg K
c1 = 4.5 J/kg K
c2 = -9.00E-03 J/kg K
c3 = 6.00E-06 J/kg K
or, csp = (-191.5) + (4.5) * T + (-9E-03) * T2 + (6E-06) * T3 [J/kg K]
[8] Bazant & Cedolin, Stability of Structures, chapter 10, “Stability of Inelastic Structures, Bifurcation and Thermodynamic Basis”
Here they present a much more rigorous thermodynamic analysis of structures (i.e. not limited to quasi-static states). Their formulation uses generalized forces and fluxes, second-order work, internal entropy production to do work of shearing bolts and fracturing beams, etc.