Ziggurat
Penultimate Amazing
- Joined
- Jun 19, 2003
- Messages
- 61,622
I didn't mistake anything.
Then why'd you say "particle's derivative" when I was talking about partial derivatives? Particles don't have derivatives. Properties of particles can have derivatives, but that's not the same thing, and it sure as hell looked like you couldn't tell the difference. And given your refusal to ever demonstrate any competence in math, well, you'll just have to accept that I won't give you the benefit of the doubt about stuff like this.
Of course, you could just provide such a demonstration, since you claim you can do math.
I asked you for a *physical description* at the atomic level of what that partial derivative related to.
In the case of liquids at negative pressures, it comes from the fact that the atoms attract each other and the container walls. So in order to expand the container, you need to do work to pull the atoms farther apart from each other and the container walls, increasing the potential energy of the system. But of course, force opposes the increase of potential energy, so you get an inwards force, and hence a negative pressure. This is really basic stuff, and you seem totally unaware of it.