Where did that come from?
Far as I know he's absolutely right in the claim that there wasn't a C02 concentration of 380ppm until fairly recently. I suppose if you take his statement as him saying that 380ppm is absolutely unprecedented in the history of the planet and then go far back enough it might've happened before, but with a more common sense interpretation of what he was saying he really wasn't misrepresenting the data we have on atmospheric CO2 concentrations.
To copy-paste another IPCC AR4 SPM chart:
What you're looking at are composites. The top one is the Siple Curve shifted 83 years to the Moana Loa CO2 meaurements so as to produce a single curve.
But no-one knows how the Siple curve was produced and how many readings above the "pre-industrial" 280ppm they erased to get the curve.
There is good evidence that ice cores are artificially deficient in carbon dioxide because of the properties of the ice the gases are found in. Other techniques such as from plant stomata, show that 6000 years ago, the CO2 concentration was ~350 ppm.
The modern value for carbon dioxide concentration is abnormally low in geological history. For long periods in the past, carbon dioxide levels were 10-20 times their current level, and were much higher even during million-years-long ice ages.