Have you actually debunked Joe Marino before calling it nonsense?
Yep. As have others. I suppose we could start with his infamously silly "ten solid reasons why the C-14 corner differs from the Shroud’s main part" where he makes all sort of nonsensical claims regarding the sampled area, regarding fluorescence, presence of madder root extract and an aluminium derived mordant and "interwoven cotton".
Alas for the believers these assertions are as sprurious as the magically invisible patch.
The fluorescence is worthless, there are several other areas (oops,I almost said 'patches') where this is equally visible (I refer you to the STURP images) . Nor does Marino (or earlier he and his wife) explain what is supposedly causing this fluorescence.
His statements regarding the presence of aluminium (present on the cloth as a mordant) is painfully stupid.
He asserts that "hydrates aluminium oxide" was detected on the cloth. Not only is this untrue, his assertion that this material (basically hydrated alumina) was used as a mordant is unsupported by historical research. In fact no-one has any samples of such usage; the common aluminium compound used as mordant was alum (impure potassium aluminium sulphate). This differentiation is important as it speaks to both Mariano's honesty (the techniques he's referring to were elementally analytical and wouldn't differentiate the compounds) and his competence with historical research (alum was commonly used, alumina was not).
BTW that data, on which Marino bases his assertions, done by Adler, Russell, Seltzer, and DeBlase, is extremely dubious; an analysis of basically a piece of pure cellulose (i.e. linen or cotton) should show approximaley equal proportions of carbon and oxygen (they are, basically, carbohydrates). But it does not. In fact they claim to have determined proportions (C/O) of 93/3.2, 66/27, 22/48, 33/43, and 21/49, which is utter garbage.
Strangely the shroudies haven't noticed this problem. Thank fully others have.
Marino claims that the magically patches area used madder as adye, presumably to match the rest of the cloth.He provides no evidence for this assertion so I didn't plan on wasting time addressing it.
He also asserts that alizarin and purpurin were present, but,again does not explain any chemical tests that substantiated these assertions.
Not satisfied with these unsupported assertions he goes on to further nonsensical claims. Specifically that a second mordant was used, claiming that calcium carbonate was used (both on the Lirey cloth and in general) to later the colour, asserting that
"Calcium compounds produce blue colours" a statement so bizarrely untrue, as easily found to be so, that it further brings into question Mariano's honesty and credibility
In fact calcium carbonate was often used with madder to
intensify its red colour, not to turn it blue, which it simply doesn't do.
I'm going to skip over the Marino assertions regarding gun Arabic being present, as They're both irrelevant and unproven by his "analysis" with further dubious claims regarding the pyrolysis products of cellulose. In passing I will mention that the cleansing of the radiocarbon samples would remove gum arabic with ease and even if Mariano's claims were true his supposed spectrographic results didn't actually match what he claims for them.......
ON to the cotton claims. I've covered most of these previously so It'll stick to Marino's specific claims, which are based on statements by Heimburger and Fanti.
By the way, these claims are based on just two fragments of single threads.
Heimburger claimed that his thread fragment (“R7") was "definitely some kind of blended thread".
While Fants suggested that the tiny amount of cotton fragments on his thread ("F15001") was due to cotton being a contaminant, probably from the environment where linen threads were prepared.
Heinburger's claims fall apart early; experts have stated that such blended thread didn't actually exist (and there are no extant examples). Others, such as Dorothy Crispino and Hilda Leynen, have pointed out that accidental contamination was almost inevitable given much thread was prepared.
So, to summarise, assertions and garbage science. Rejected.
You want to bring Ray Rogers work into the mix?
Not particularly. His attempts at science were blinded by religious belief.
But given that Marino and Benford based their nonsense on his.....
How do you feel about his 'Black Forrest elves'?
What about what Riggi di Numana, who found "fibres of other origins had become mixed up with the original fabric and could have led to erroneous readings in the dating experiment."
Sigh. Poor Giovanni. Persona-non-grata amongst the shroudies because of his involvement with the radiocarbon dating.
It's also a pity he didn't provide evidence for his assertions.....