Not so. It emits highly toxic vapours and projectile jets of flames with debris as well, as the unstable cells form dendrites. If you douse it with water, the water becomes highly toxic with hydroflourides.
See here a van in thermal runaway at Heathrow:
https://youtu.be/mIIdMkwKLp4?si=Fm9cS6qrRoslrb0i
Mercedes Vito electric van in thermal runaway near Heathrow Airport
emits highly toxic vapours1 and projectile jets of flames with debris as well, as the unstable cells form dendrites2. If you douse it with water, the water becomes highly toxic with hydroflourides.3
1. As do many fires
2. The dendrites form within the cells and contribute to the short circuit that leads to the fire, but it's not anything particularly scary of itself.
3. This can be a problem
But it's somewhat irrelevant as the fire started in a diesel vehicle.

