S. Szpak, P.A. Mosier–Boss,1 and R.D. Boss
Naval Command, Control and Ocean Surveillance Center RDT & E Division San Diego, CA 92152 - 5000
and
J.J.Smith
Department of Energy, Washington, DC 20585
ABSTRACT
Evidence for tritium production in the Pd/D system under cathodic polarization is presented. A comparison of the observed distribution and that calculated, based upon the conservation of mass, leads to the conclusion that tritium is produced sporadically at an estimated rate of ca 103–104 atoms per second. The results of several runs are interpreted by employing the concept of an electrode/electrolyte interphase and the accepted kinetics of hydrogen evolution. Observation of burst-like events followed by longer periods of
inactivity yield poor reproducibility when distributions are averaged over the total time of electrolysis.
http://www.newenergytimes.com/v2/library/1998/Szpak-On-the-behavior.pdf