Well, if you call it the law of "great" numbers, you either don't know it or studied it in another language than English (where it is known as the law of large numbers). For any continuous random variable, i.e. any quantity you can measure with indefinite precision without counting, you cannot put any positive weight to a single point, because the axioms of probability need the sum of those weights to be 1, and you can only do that on quantities that are countable. For example, the probability that it is 15 degrees outside is zero, because it could be 15.01, 14.99, 15.001, 15.0001, 14.999, etc. ad infinitum if we could measure it with enough precision (and it is impossible to enumerate all the possible values of the temperature). So the probability of any point is actually 0.
So the temperature of 15 degrees is possible, but it has probability 0. However, you can give a positive probability to an interval, i.e. the set of all points between a and b (say), and you can define with that a probability density function, which has similar properties to probability mass functions, but assigns a density, not probability, to a point.
So, while there is a temperature outside, and it has to take a value, the probability of any value for that temperature is 0, though the probability that it falls between some values a and b can be positive. However, some temperatures are impossible, particularly anything below absolute zero. Those temperatures have probability 0 and density 0 as they fall outside the support of the temperature range.
Of course, continuous random variables are not the only "creatures" where possible and probability 0 intersect. They are just the most common (and realistic) examples.