Let me put it this way: If you only have one material, say iron, and you switch on the voltage, is it true that the electric-field starts to act near-instantaneously at every point along the conductor, and that the charge-carriers must thus accelerate equally at every position?
Your intuition on this is
terrible, Johan. You know darn well that, given equal electric fields in copper and in iron, you'll get more current in the copper and less in the iron.
Yet suddenly you think it's super-important to consider the
first twenty femtoseconds---yes, that's the number---during which this may not be true. Let me be blunt: you've been ignoring these twenty femtoseconds
all along, and you've just discovered them now because you're flailing for
any excuse to ignore it.
The fact is, Johan: sure, maybe there's a 20-fs super-transient
before Ohm's Law tells you how much current there is. Fine. Also, changes in electric field only propagate at about 10 microns per 20fs, did we consider that?
So, yeah, during the first 20fs maybe the currents are equal.
Therefore during the first 20fs the electric fields are also equal. . This is the problem, Johan. If you find an approximation that allow you to ignore the material differences, and ignoring the fact that the materials respond differently to electric fields ... well, you're never going to find a reason that the copper's electric field
winds up lower than the iron's.
Of course, it's easy---even if, as you now seem to insist, we look at scattering instead of Ohm's Law. We turn on a field, constant everywhere. In the iron, charges accelerate. In the copper, charges accelerate. The copper charges continue accelerating for 20fs. The iron charges scatter after 10 fs. Look at the copper-iron boundaries, then: charges are arriving from the left at high speed but are getting scattered just as they try to leave. (Or vice-versa.) That's
unequal currents, like we've been saying all along. Unequal currents means charges start piling up at the boundary. The charges piling up at the boundary begin reducing the electric field, or repelling the incoming charges (vice-versa for the other contact) until charges arrive from the left at the same rate as charges that leave on the right---you get to an equilibrium where the incoming charges are arriving slowly (because they have long mean free paths in the weak field) and the departing charges are departing slowly (because they have short MFPs in the strong field). The equilibrium conditions stop the pileup from
getting worse, but they don't clear away the pileup that's already there.
Recall that we've already done this---remember how you insisted on using Drude's Law, then Newton's Law, instead of Ohm's? What made you think that "zooming in" to these 20fs would change the answer
this time when it didn't last time?