Originally Posted by
Christopher7
1) It was NOT a
"high temperature atmosphere"*
Smoldering fires burn at about 500-600
°C.
*WTC7 debris pile
Now you have 'defined' what counts as a high temperature atmosphere?
Do you have a source which explains this rule you have established?
FEMA 403 Appendix C C.3 Summary for Sample 1
1.The thinning of the steel occurred by a high-temperature corrosion due to a combination of oxidation and sulfidation.
2.
Heating of the steel into a hot corrosive environment approaching 1000°C (1800°F) results in the formation of a eutectic mixture of iron, oxygen and sulfur that liquefied the steel.
The abstract of this article:
LINK seems to be concerned with high temperature corrosion resistance applications on steel in a temperature range of 500-700 oC
Abstract:
Relates to the development of high temperature resistant coating applicable in the temperature range of 500°C to 700°C. A12O3, TiO2 and ZrO2 have been incorporated in aluminium phosphate and ivory-400 used as binders. Aluminium phosphate as a binder has not performed well in comparison to ivory-400.
Aims mainly to study and to highlight the behaviour of the corrosion-resistant coating at high temperature.
So where have you dawn the line to distinguish high temperature environments from the non?
There is no "line" but 500-600°C is 400°C below the "approaching 1000°C" necessary to result in "the formation of a eutectic mixture of iron, oxygen and sulfur that liquefied the steel."
Corrosive gases
Air, oxygen:, Steam:, Carbon, carbon oxides and methane:, Sulfur containing Gases:[etc.]
These take place in small amounts over a period of time.
The "
high-temperature corrosion due to a combination of oxidation and sulfidation" is unique to this beam.
There have been more intense, longer lasting fires, and there is no other reported case of this happening.
Gypsum decomposes when exposed to the elements and constant heat source.
The gypsum [drywall/wallboard] falls apart but the gypsum molecules don't. The chemical bonds are very strong. If gypsum released its sulfur in a fire, it wouldn't be used for fireproofing.
Just for S&G, this is cool:
[left click and hold on molecule, as you move the mouse around, you can rotate the molecule in any direction]
CaSO4
http://www.webmineral.com/jpowd/JPX/jpowd.php?target_file=Gypsum_1.jpx
Gypsum
[the roller will zoom in and out on this one]
http://openmopac.net/data_solids/Gypsum%20(CaSO4_2H2O)_Jmol.html