Being "refuted" by Heller and Alder wouldn't bother McCrone at all. Why? Well because they didn't refute him to begin with. His opinion of Heller and Adler is very low.Hedler and Alder disagree with McCrone.
Also, if there was pigment in the form of ochre or vermillion, there would be impurities associated with pigment.
"The results of these metal tests are in agreement with the general conclusion> reached by X-ray fluoresccnce(l3) which found only ill Ca, Fe and Sr on the Shroud above truce levels. However, the chemical tesiing allows us 10 be much more specific in the assignment of actual structures of the metallic compounds present. These results do not support the hypothesis that the image is painted with inorganic pigments."
Sorry for the formatting but McCrone was debunked before the shroud was dated.
Regarding Heller and Adler's x-ray fluorescence work McCrone says:
"These incredible suggestions [By Heller and Alder] show how they do struggle to avoid the obvious explanation and source of the red image - artist pigments." (Judgement Day for the Shroud of Turin, p. 166)
On the same page McCrone refers to Heller and Adler's work has: "This I find incomprehensible nonsense".
It seems Heller and Alder were in fact debunked. But then they apparently became true believers.
On page 171 McCrone says:
"I gave up arguing with STURP in 1980. I found their intransigence and lack of understanding of the true nature of this image and their stubborn lack of objectivity affected my digestion."
"It seemed best to go my own way and try to ignore their efforts to prove the "Shroud" to be authentic at all costs. They remain to this day (1996), resolute in their faith that the "Shroud" is the real Shroud of Christ's crucifixion."
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